Mattias Eriksson
Blekinge Institute of Technology, Sweden
Title: Total statistical weights of atoms and ions
Biography
Biography: Mattias Eriksson
Abstract
The total statistical weight of an atom or ion equals the number of energy levels of the atom or ions when subjected to a magnetic or an electric field (Zeeman or Stark eff ect). In the theoretical limit of zero perturbation the number of bound levels goes to infi nity, as does the total statistical weight. With a known perturbation the statistical weight is fi nite and can be calculated by summating 2J+1 for all levels which are degenerated in zero electric and magnetic fields, the m levels. The structure of the J states depends on the coupling scheme, the Glebsch-Gordon coeffi cients. The number of levels for each J corresponding to a principal quantum number n is independent of the scheme. Here I will present one formula for the total statistical weight between any chosen principal quantum numbers for any Rydberg Sequence. The statistical weight contribution is surprisingly easy: f(Lp,Sp)∙n2, where Lp and Sp are the orbital and spin angular momentum quantum numbers of the parent term to the Rydberg Sequence. Th is helps improve the calculations of atomic and ionic partition functions. Each m-level makes the contribution of unity to the statistical weight and its contribution to the partition function is exp(-E/kT), where E, k and T are the excitation energy of the level, the Boltzmann's constant and the temperature. Only a tiny fraction of the energy levels of atoms and ions are known (observed) for high values of the principal quantum number so the partition function must be calculated numerically. For low values of perturbation, like in stellar plasmas there are sometimes thousands of bound levels having negligible energy diff erences. Th e statistical weights of those levels are calculated with this formula and then multiplied with the exp(-E/kT) factor to get their contribution to the partition function.